Magnesium Hexafluorophosphate Contact Joyce Luo sales03@chemfish.com www.chemfish.com Mg(PF 6 ) 2 -based electrolytes for Mg-ion batteries have not received the same attention as the analogous LiPF 6 -based electrolytes used in most Li-ion cells owing to the perception that the PF 6 – anion decomposes on and passivates Mg electrodes. No synthesis of the Mg(PF 6 ) 2 salt has been reported, nor have its solutions been studied electrochemically. Here, we report the synthesis of the complex Mg(PF 6 ) 2 (CH 3 CN) 6 and its solution-state electrochemistry. Solutions of Mg(PF 6 ) 2 (CH 3 CN) 6 in CH 3 CN and CH 3 CN/THF mixtures exhibit high conductivities (up to 28 mS·cm –1 ) and electrochemical stability up to at least 4 V vs Mg on Al electrodes. Contrary to established perceptions, Mg electrodes are observed to remain electrochemically active when cycled in the presence of these Mg(PF 6 ) 2 -based electrolytes, with no fluoride (i.e., MgF 2 ...
TECHNICAL DATA CAS No: 1120-71-4 Synonyms: 3-Hydroxy-1-propanesulfonic acid gamma-sultone; 2,2-Dioxide 1,2-oxathiolane; 1,3-Trimethylene sultone Product Code: FP27191 MDL No: MFCD00005355 Chemical Formula: C 3 H 6 O 3 S Molecular Weight: 122.14 1,3-Propane sultone is used as a chemical intermediate. No information is available on the acute (short-term), chronic (long-term), reproductive, developmental, and carcinogenic effects of 1,3-propane sultone in humans. In rodents exposed to 1,3-propane sultone via gavage (experimentally placing the chemical in the stomach) and intravenous injection, tumors of the brain and other central nervous system (CNS) tissues have been observed. Leukemia, and tumors of the ear duct, small intestine, kidneys, lung, mammary gland, uterus, and skin have been reported in rodents exposed via gavage, injection, or dermal contact. The International Agency for Research on Cancer (IARC) has classifi...
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